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The First Law of Thermodynamics states that:


A) Molecules move faster as temperature increases.
B) The total entropy of the universe is increasing.
C) Energy transfers from hotter objects to cooler objects.
D) Samples with different temperatures that come in contact with one another will reach thermal equilibrium.
E) The total energy of the universe is constant.

F) D) and E)
G) A) and B)

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Based on the following thermochemical equation, which statement is false? Based on the following thermochemical equation, which statement is false?   A)  The thermochemical equation represents a physical change. B)  The enthalpy change for the gas condensing into a liquid is known. C)  The internal energy of the surroundings increases. D)  The pressure for the process is known. E)  The enthalpy change is endothermic.


A) The thermochemical equation represents a physical change.
B) The enthalpy change for the gas condensing into a liquid is known.
C) The internal energy of the surroundings increases.
D) The pressure for the process is known.
E) The enthalpy change is endothermic.

F) A) and E)
G) A) and D)

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Determine the heat of reaction for the process Determine the heat of reaction for the process     using the information given below:   A)  -1074.0 kJ B)  -22.0 kJ C)  22.2 kJ D)  249.8 kJ E)  1074.0 kJ using the information given below: Determine the heat of reaction for the process     using the information given below:   A)  -1074.0 kJ B)  -22.0 kJ C)  22.2 kJ D)  249.8 kJ E)  1074.0 kJ


A) -1074.0 kJ
B) -22.0 kJ
C) 22.2 kJ
D) 249.8 kJ
E) 1074.0 kJ

F) C) and D)
G) B) and C)

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What is the enthalpy change when 175 g of C3H8 are burned in excess O2? What is the enthalpy change when 175 g of C<sub>3</sub>H<sub>8</sub> are burned in excess O<sub>2</sub>?   A)  -1.71 × 10<sup>7</sup> kJ B)  -1.79 × 10<sup>-3</sup> kJ C)  -3.47 × 10<sup>0</sup> kJ D)  -3.89 × 10<sup>5</sup> kJ E)  -8.82 × 10<sup>3</sup> kJ


A) -1.71 × 107 kJ
B) -1.79 × 10-3 kJ
C) -3.47 × 100 kJ
D) -3.89 × 105 kJ
E) -8.82 × 103 kJ

F) All of the above
G) B) and E)

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Which of the following is not an example of kinetic energy?


A) the motion of a molecule
B) a golf ball sitting on a tee
C) the vibration of an object
D) a brick falling from the top of a building
E) the motion of electrons through a wire

F) All of the above
G) B) and E)

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Based on the following thermochemical equation below, which statement is false? Based on the following thermochemical equation below, which statement is false?   A)  For the reverse process, DH° = + 46.11 kJ. B)  The value of 46.11 kJ applies to the formation of two moles of NH<sub>3</sub>. C)  The value of 92.22 kJ applies to the reaction of two moles of N<sub>2</sub> and three moles of H<sub>2</sub>. D)  Per mole of N<sub>2</sub>, DH° = -46.11 kJ. E)  Per mole of H<sub>2</sub>, DH° = -15.37 kJ.


A) For the reverse process, DH° = + 46.11 kJ.
B) The value of 46.11 kJ applies to the formation of two moles of NH3.
C) The value of 92.22 kJ applies to the reaction of two moles of N2 and three moles of H2.
D) Per mole of N2, DH° = -46.11 kJ.
E) Per mole of H2, DH° = -15.37 kJ.

F) A) and B)
G) A) and C)

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Determine the quantity of ice required to absorb exactly 50 kJ of energy when the ice warms from -50.0°C to -10.0°C (specific heat of ice = 2.06 J g-1 °C-1) .


A) 0.485 g
B) 0.607 g
C) 485 g
D) 607 g
E) 2.43 × 103 g

F) None of the above
G) A) and E)

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A 0.100 mole sample of CH4 reacts completely in a calorimeter having a heat capacity of 783 J/°C. The calorimeter contains 254 g of water. Determine the temperature increase of the calorimeter. The specific heat of water = 4.184 J g-1 °C-1. A 0.100 mole sample of CH<sub>4</sub> reacts completely in a calorimeter having a heat capacity of 783 J/°C. The calorimeter contains 254 g of water. Determine the temperature increase of the calorimeter. The specific heat of water = 4.184 J g<sup>-1</sup> °C<sup>-1</sup>.   A)  4.35 × 10<sup>-3</sup>°C B)  7.56°C C)  10.2°C D)  31.6°C E)  43.5°C


A) 4.35 × 10-3°C
B) 7.56°C
C) 10.2°C
D) 31.6°C
E) 43.5°C

F) A) and B)
G) A) and C)

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E

The complete combustion of 1.47 g of methanol produces 29.3 kJ of heat. Determine the DH° for the reaction and its sign. The complete combustion of 1.47 g of methanol produces 29.3 kJ of heat. Determine the DH° for the reaction and its sign.   A)  -938 kJ B)  -638 kJ C)  -1.35 kJ D)  +638 kJ E)  +938 kJ


A) -938 kJ
B) -638 kJ
C) -1.35 kJ
D) +638 kJ
E) +938 kJ

F) A) and B)
G) B) and D)

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How much energy is required to melt 10.0 g of ice at 0.0°C, warm it to 100.0°C and completely vaporize the sample? The enthalpy of fusion of ice = 333 J g-1 at 0 °C; the specific heat of water = 4.184 J g-1 °C-1; the heat of vaporization of water = 2260 J g-1 at 100 °C.


A) 30100 J
B) 22600 J
C) 4180 J
D) 3330 J
E) 343 J

F) A) and B)
G) A) and C)

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Which of the following is an example of potential energy?


A) atoms vibrating back and forth around a specific location
B) a rock rolling down a mountain
C) a fat molecule stored in the body
D) electrons flowing through an electrical conductor
E) the sound of a dog barking

F) A) and C)
G) A) and D)

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C

A 20.0 g sample of aluminum (specific heat = 0.902 J g-1 °C-1) with an initial temperature of 48.6°C is heated with 427 J of energy. What is the final temperature of the sample?


A) 74.8°C
B) 72.3°C
C) 26.2°C
D) 24.9°C
E) 23.7°C

F) B) and E)
G) B) and D)

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In a(n) _____________ reaction, the energy of bond breaking is greater than the energy of bond making.

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Which substance has the highest molar heat capacity?


A) copper (specific heat = 0.385 J g-1 °C-1)
B) iron (specific heat = 0.451 J g-1 °C-1)
C) silver (specific heat = 0.232 J g-1 °C-1)
D) lead (specific heat = 0.128 J g-1 °C-1)
E) aluminum (specific heat = 0.902 J g-1 °C-1)

F) All of the above
G) A) and B)

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Determine the amount of heat required to raise the temperature of a 153 g bar of gold by 50.0°C (specific heat of gold = 0.128 J g-1 °C-1) .


A) 490 J
B) 979 J
C) 1.47 × 103 J
D) 7.65 × 103 J
E) 5.98 × 104 J

F) A) and D)
G) A) and B)

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Determine the heat of reaction for the process Determine the heat of reaction for the process    using the information given below:   A)  -295.3 kJ B)  -29.2 kJ C)  +29.2 kJ D)  +295.3 kJ E)  +398.4 kJ using the information given below: Determine the heat of reaction for the process    using the information given below:   A)  -295.3 kJ B)  -29.2 kJ C)  +29.2 kJ D)  +295.3 kJ E)  +398.4 kJ


A) -295.3 kJ
B) -29.2 kJ
C) +29.2 kJ
D) +295.3 kJ
E) +398.4 kJ

F) B) and E)
G) B) and D)

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Which statement about energy is false?


A) Thermodynamics is the science of working and heating processes.
B) Working and heating are processes that transfer energy.
C) Chemical reactions are processes that transfer energy
D) The chemical energy of foods and fuels is a type of potential energy.
E) The thermal energy of nanoscale objects is a type of potential energy.

F) C) and E)
G) All of the above

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The quantity of energy required to increase the temperature of one gram of a sample by 1°C is called the _____________.

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specific heat

In an endothermic reaction, heat is transferred from the _____________ to the _____________.

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surroundin...

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The temperature of a 21.6 g sample of a metal rises 6.04°C when 58.8 J of energy is applied to it. What is the identity of the metal?


A) silver (specific heat = 0.232 J g-1 °C-1)
B) copper (specific heat = 0.385 J g-1 °C-1)
C) iron (specific heat = 0.451 J g-1 °C-1)
D) lead (specific heat = 0.128 J g-1 °C-1)
E) aluminum (specific heat = 0.902 J g-1 °C-1)

F) C) and D)
G) B) and E)

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