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Identify the molecular structure of the nitrate ion, Identify the molecular structure of the nitrate ion,   , and the hybridization of the N atomic orbitals. , and the hybridization of the N atomic orbitals.

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What is the valence electron molecular orbital electron configuration of C2?


A) What is the valence electron molecular orbital electron configuration of C<sub>2</sub>? A)    B)    C)    D)    E)
B) What is the valence electron molecular orbital electron configuration of C<sub>2</sub>? A)    B)    C)    D)    E)
C) What is the valence electron molecular orbital electron configuration of C<sub>2</sub>? A)    B)    C)    D)    E)
D) What is the valence electron molecular orbital electron configuration of C<sub>2</sub>? A)    B)    C)    D)    E)
E) What is the valence electron molecular orbital electron configuration of C<sub>2</sub>? A)    B)    C)    D)    E)

F) B) and E)
G) All of the above

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According to the molecular orbital energy level diagram below, which one of the following statements is not correct about NO, NO+, and According to the molecular orbital energy level diagram below, which one of the following statements is not correct about NO, NO<sup>+</sup>, and   ?   A)  The bond order in NO is 2.5. B)  NO<sup>+</sup> has the shortest bond. C)  Only one of these species is paramagnetic. D)  The bond order in   is 2.0. E)    has the weakest bond. ? According to the molecular orbital energy level diagram below, which one of the following statements is not correct about NO, NO<sup>+</sup>, and   ?   A)  The bond order in NO is 2.5. B)  NO<sup>+</sup> has the shortest bond. C)  Only one of these species is paramagnetic. D)  The bond order in   is 2.0. E)    has the weakest bond.


A) The bond order in NO is 2.5.
B) NO+ has the shortest bond.
C) Only one of these species is paramagnetic.
D) The bond order in According to the molecular orbital energy level diagram below, which one of the following statements is not correct about NO, NO<sup>+</sup>, and   ?   A)  The bond order in NO is 2.5. B)  NO<sup>+</sup> has the shortest bond. C)  Only one of these species is paramagnetic. D)  The bond order in   is 2.0. E)    has the weakest bond. is 2.0.
E) According to the molecular orbital energy level diagram below, which one of the following statements is not correct about NO, NO<sup>+</sup>, and   ?   A)  The bond order in NO is 2.5. B)  NO<sup>+</sup> has the shortest bond. C)  Only one of these species is paramagnetic. D)  The bond order in   is 2.0. E)    has the weakest bond. has the weakest bond.

F) A) and C)
G) B) and D)

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Which of the following molecules is linear?


A) H2O
B) H2S
C) ICl3
D) I3-
E) SO2

F) A) and B)
G) A) and D)

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Which of the following molecules has a carbon atom that is sp3 hybridized?


A) C2H2
B) H2CO
C) CH3Cl
D) C2H4
E) C2H2Cl2

F) C) and D)
G) B) and D)

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Predict the bond order of the NO- molecular ion.


A) 2
B) 2.5
C) 3
D) 1
E) 1.5

F) B) and E)
G) None of the above

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A

What hybridization is needed to describe the square planar molecular geometry of KrF4?


A) sp3
B) sp3d
C) sp3d2
D) sp2
E) sp

F) C) and D)
G) A) and D)

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Which of the following compounds has a trigonal bipyramidal shape?


A) ICl3
B) BrF5
C) PCl5
D) PH3
E) SiF4

F) B) and E)
G) All of the above

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For which one of the following molecules (BF3, CF4, NF3, OF2, XeF4) is the electron geometry tetrahedral and the molecular geometry triangular pyramidal? Draw its Lewis structure with the correct bond angles.

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blured image In the diagram each...

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Which of the following molecules is paramagnetic?


A) F2
B) O2
C) C2
D) Be2
E) "C2"

F) A) and B)
G) B) and C)

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Which of the following has a local molecular geometry about a carbon atom that is trigonal planar?


A) CH3CH2OH
B) CH3OH
C) C2H4
D) CH3OCH3
E) C2H2

F) B) and C)
G) A) and B)

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Which of the following molecules has a trigonal pyramid shape?


A) KrF4
B) COCl2
C) SeO32-
D) NH4+
E) O3

F) C) and D)
G) B) and D)

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What is the hybridization of the oxygen in the H3O+ ion?


A) sp2
B) sp3
C) sp3d
D) sp
E) sp3d2

F) B) and E)
G) D) and E)

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Boron nitride, BN, is a new high tech material. According to the molecular orbital energy level diagram below, which one of the following statements is not correct about boron nitride? Boron nitride, BN, is a new high tech material. According to the molecular orbital energy level diagram below, which one of the following statements is not correct about boron nitride?   A)  The bond order in BN is 2.0. B)  The cation BN<sup>+</sup> has a longer bond than BN. C)  BN is paramagnetic. D)  The bond order in the cation BN<sup>+</sup> is 1.5. E)  The anion BN<sup>-</sup> has a weaker bond than BN.


A) The bond order in BN is 2.0.
B) The cation BN+ has a longer bond than BN.
C) BN is paramagnetic.
D) The bond order in the cation BN+ is 1.5.
E) The anion BN- has a weaker bond than BN.

F) B) and D)
G) B) and C)

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Predict the following three bond angles and give your rationale: N - C - C, O - C Predict the following three bond angles and give your rationale: N - C - C, O - C   O, and C - O - H. These bonding patterns appear in amino acids. O, and C - O - H. These bonding patterns appear in amino acids.

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N - C - C: 109° steric number of central C is 4 O - C 11eaae02_08c0_ec3c_95d8_d59ad3716450_TB3833_11 O, 120° steric number of C is 3 C - O - H: near but less than 109° steric number of O is 4 but repulsion by lone pairs decreases angle

Ethanol has the formula CH3CH2OH. The central carbon atom has a _____ local molecular geometry and _____ hybridization.


A) trigonal planar; sp
B) tetrahedral; sp3
C) tetrahedral; sp2
D) seesaw; sp2
E) seesaw, sp3

F) None of the above
G) D) and E)

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Of the following molecules (O3, SCl2, SO2, CS2, and CO2) which ones do you predict to have a bond angle of 180°?

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Which of the following molecules or ions is not polar?


A) O3
B) H2O
C) SO2
D) I3-
E) S3

F) A) and B)
G) D) and E)

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Use the 1s orbital of hydrogen to form atomic orbitals for H2 and draw the molecular orbital energy level diagram. Label the energy levels with the MO symbols. Which of the following species of hydrogen would you predict to be stable based on your energy level diagram? Explain. H22+, H2+, H2, H2-, H22-

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*____________...

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Predict the bond order of the NO+ molecular ion.


A) 2
B) 2.5
C) 3
D) 1
E) 1.5

F) A) and E)
G) D) and E)

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C

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