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At 200 K, the molecules or atoms of an unknown gas, X, have an average velocity equal to that of Ar atoms at 400 K. What is X? (Assume ideal behavior.)


A) CO
B) F2
C) He
D) HF
E) HBr

F) B) and E)
G) A) and E)

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Calculate the density of nitrogen at STP.


A) 1.25 g/L
B) 0.625 g/L
C) 0.312 g/L
D) 1.60 g/L
E) 0.800 g/L

F) None of the above
G) A) and E)

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Consider two samples of helium in separate containers of the same volume. Sample 1 has an absolute temperature four times that of Sample 2. Both samples are at the same pressure. Calculate the ratio Z1/Z2.


A) 4:1
B) 2:1
C) 1:2
D) 1:4
E) 1:1

F) B) and D)
G) C) and D)

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Equimolar amounts of the gases N2 and H2 are mixed in a closed container fitted with a piston (allowing the volume of the container to change, thus keeping the pressure constant) . Calculate the ratio of the final volume of the container to the initial volume of the container when the reaction N2 + 3H2 2NH3 goes to completion.


A) 1
B) 2/3
C) 3/2
D) 1/3
E) none of these

F) B) and C)
G) A) and D)

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Consider two samples of helium in separate containers of the same volume. Sample 1 has an absolute temperature four times that of Sample 2. Both samples are at the same pressure. Calculate the ratio n1/n2.


A) 2:1
B) 1:1
C) 1:2
D) 4:1
E) 1:4

F) B) and E)
G) D) and E)

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Consider two samples of gas at the same volume and temperature that each contains 1.0 mol of gas. Sample A contains H2 and sample B contains an unknown gas. The ratio of the impacts per second of gas A with the walls of the container to the impacts per second of gas B with the walls of the container is 4. Identify gas B.


A) Ar
B) CO2
C) He
D) Ne
E) O2

F) A) and C)
G) A) and E)

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Body temperature is about 308 K. On a cold day, what volume of air at 273 K must a person with a lung capacity of 2.00 L breathe in to fill the lungs?


A) 1.13 L
B) 2.26 L
C) 1.77 L
D) 3.54 L
E) none of these

F) A) and E)
G) A) and D)

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Consider three 1.0-L flasks at STP. Flask A contains Ar gas, flask B contains Kr gas, and flask C contains H2 gas. In which flask do the gas particles have the highest average velocity?


A) flask A
B) flask B
C) flask C
D) The gas particles in all the flasks have the same average velocity.
E) The gas particles in two of the flasks have the same average velocity.

F) A) and B)
G) A) and C)

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What volume of carbon dioxide measured at STP will be formed by the reaction of 1.30 mol of oxygen with 9.00 10-1 mol of ethyl alcohol (CH3CH2OH) ?


A) 91.9 L
B) 8.70 L
C) 28.0 L
D) 19.4 L
E) 40.3 L

F) A) and B)
G) B) and C)

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Consider three 1-L flasks at the same temperature and pressure. Flask A contains CO gas, flask B contains N2 gas, and flask C contains O2 gas. In which flask do the molecules have the greatest kinetic energy?


A) flask A
B) flask B
C) flask C
D) The molecules in all the flasks have the same kinetic energy.
E) The molecules in two of the flasks have the same kinetic energy.

F) B) and D)
G) A) and B)

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A 259.6-L cylinder contains 63.5% He(g) and 36.5% Kr(g) by mass at 22.0°C and 1.25 atm total pressure. What is the mass of He in this container?


A) 30.0 g
B) 52.2 g
C) 82.2 g
D) 700 g
E) 34.1 g

F) A) and B)
G) C) and D)

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The molar mass of gas Y is


A) 89.0 g/mol.
B) 56.0 g/mol.
C) 157 g/mol.
D) 140. g/mol.
E) 125 g/mol.

F) A) and E)
G) A) and B)

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Near sea level, the atmosphere is composed of 78% nitrogen and 20% oxygen. Other trace gases make up the remaining 2%. At room temperature,


A) all the gas molecules move at the same speed.
B) the nitrogen gas molecules, on average, move faster than the oxygen molecules.
C) the nitrogen gas molecules, on average, move slower than the oxygen molecules.
D) some nitrogen gas molecules could move faster than some of the oxygen gas molecules.
E) some nitrogen gas molecules could move slower than some of the oxygen molecules.
F) B and D
G) C and D
H) B, D , and E

I) A) and G)
J) None of the above

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Which gas, He or H2O vapor, has the lower value of a in the van der Waals equation?


A) H2O
B) He
C) The two gases have the same value of a.
D) It depends on the conditions of pressure and temperature.

E) All of the above
F) A) and B)

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A mixture of KCl and KClO3 weighing 1.80 g was heated; the dry O2 generated occupied 1.40 102 mL at STP. What percent of the original mixture was KClO3? KClO3 decomposes as follows: 2KClO3(s) 2KCl(s) + 3O2(g)


A) 37.2%
B) 72.6%
C) 42.6%
D) 63.8%
E) 28.4%

F) D) and E)
G) A) and E)

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Suppose a sealed flask contains 1.0 L of oxygen gas that is completely converted to ozone (O3) at the same temperature. Calculate the ratio of the new pressure to the original pressure and the ratio of the number of impacts of ozone molecules with the walls of the container to the number of impacts of oxygen molecules with the walls of the container.

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At 1000°C and 10. torr, the density of a certain element in the gaseous state is 2.9 10-3 g/L. The element is


A) Ne.
B) Ar.
C) He.
D) Na.
E) Hg.

F) C) and D)
G) B) and D)

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Magnesium metal reacts with hydrochloric acid to form aqueous magnesium chloride and hydrogen gas. An excess of magnesium is reacted with 20.0 mL of 3.00 M hydrochloric acid, and all of the hydrogen is collected in a balloon at 25°C and 1.00 atm. What is the expected volume of the balloon?


A) 0.734 L
B) 1.47 L
C) 0.672 L
D) 22.4 L
E) 1.34 L

F) B) and C)
G) A) and E)

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Four identical 1.0-L flasks contain the gases He, Cl2, CH4, and NH3, each at 0°C and 1 atm pressure. -Which gas has the highest density?


A) NH3
B) CH4
C) Cl2
D) He
E) All the gases have the same density.

F) A) and C)
G) A) and B)

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Consider three 1-L flasks at the same temperature and pressure. Flask A contains CO gas, flask B contains N2 gas, and flask C contains O2 gas. Which contains the lowest density?


A) flask A
B) flask B
C) flask C
D) All are the same.
E) Two of the flasks contain gases at the same density.

F) A) and B)
G) C) and D)

Correct Answer

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